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Soot formation and oxidation are complex and competing processes during diesel combustion. The balance between the two processes and their history determines engine-out soot values. Besides the efforts to lower soot formation with measures to influence the flame lift-off distance for example or to use HCCI-combustion, enhancement of late soot oxidation is of equal importance for low-λ diffusion-controlled low emissions combustion with EGR. The purpose of this study is to investigate soot oxidation in a heavy duty diesel engine by statistical analysis of engine data and in-cylinder endoscopic high speed photography together with CFD simulations with a main focus on large scale in-cylinder gas motion. Results from CFD simulations using a detailed soot model were used to reveal details about the soot oxidation.

In this paper, an experimental and numerical analysis of combustion process and knock occurrence in a small displacement spark-ignition engine is presented. A wide experimental campaign is preliminarily carried out in order to fully characterize the engine behavior in different operating conditions. In particular, the acquisition of a large number of consecutive pressure cycle is realized to analyze the Cyclic Variability (CV) effects in terms of Indicated Mean Effective Pressure (IMEP) Coefficient of Variation (CoV). The spark advance is also changed up to incipient knocking conditions, basing on a proper definition of a knock index. The latter is estimated through the decomposition and the FFT analysis of the instantaneous pressure cycles. Contemporary, a quasi-dimensional combustion and knock model, included within a whole engine one-dimensional (1D) modeling framework, are developed. Combustion and knock models are extended to include the CV effects, too.

The possibilities of operating a direct injection Diesel engine in HCCI combustion mode with early injection of conventional Diesel fuel were investigated. In order to properly phase the combustion process in the cycle and to prevent knock, the geometric compression ratio was reduced from 17.0:1 to 13.4:1 or 11.5:1. Further control of the phasing and combustion rate was achieved with high rates of cooled EGR. The engine used for the experiments was a single cylinder version of a modern passenger car type common rail engine with a displacement of 480 cc. An injector with a small included angle was used to prevent interaction of the spray and the cylinder liner. In order to create a homogeneous mixture, the fuel was injected by multiple short injections during the compression stroke. The low knock resistance of the Diesel fuel limited the operating conditions to low loads. Compared to conventional Diesel combustion, the NOx emissions were dramatically reduced.

The influence of ethanol content in gasoline on speciated emissions from a direct injection stratified charge (DISC) SI engine is assessed. The engine tested is a commercial DISC one that has a wall guided combustion system. The emissions were analyzed using both Fourier transform infrared (FTIR) spectroscopy and conventional emission measurement equipment. Seven fuels were compared in the study. The first range of fuels was of alkylate type, designed to have 0, 5, 10 and 15 % ethanol in gasoline without changing the evaporation curve. European emissions certification fuel was tested, with and without 5 % ethanol, and finally a specially blended high volatility gasoline was also tested. The measurements were conducted at part-load, where the combustion is in stratified mode. The engine used a series engine control unit (ECU) that regulated the fuel injection, ignition and exhaust gas recirculation (EGR).

Future emission legislation will require substantial reductions of NOx and particulate matter (PM) emissions from diesel engines. The combustion and emission formation in a diesel engine is governed mainly by spray formation and mixing. Important parameters governing these are droplet size, distribution, concentration and injection velocity. Smaller orifices are believed to give smaller droplet size, even with reduced injection pressure, which leads to better fuel atomization, faster evaporation and better mixing. In this paper experiments are performed on a single cylinder heavy-duty direct injection diesel engine with three nozzles of different orifice diameters (Ø0.227 mm, Ø0.130 mm, Ø0.090 mm). Two loads (low and medium) and three speeds were investigated. The test results confirmed a substantial reduction in HC and soot emissions at lower loads for the small orifices.

This work investigates the influence of fuel parameters on deposit formation and emissions in a four-cylinder direct injection stratified charge (DISC) SI engine. The engine tested is a commercial DISC engine with a wall-guided combustion system. The combustion chamber deposits (CCDs) were analyzed with gas chromatography / mass spectrometry as well as thickness and mass measurements. Intake valve deposits (IVDs) were analyzed for mass, while internal injector deposits were evaluated using spray photography. The CCD build-up was obtained with the CEC1 F-020-A-98 performance test for evaluation of the influence of fuels and additives on IVDs and CCDs in port fuel injected SI engines. The 60 h test is designed to simulate city driving. Four fuels were compared in the study: a base gasoline, with and without a fuel additive, a specially blended high volatility gasoline, and a fuel representing the worst case of European gasolines; neither of the latter two had additives.

A single-cylinder engine was operated in HCCI combustion mode with different kinds of commercial fuels. The HCCI combustion was generated by creating a negative valve overlap (early exhaust valve closing combined with late intake valve opening) thus trapping a large amount of residuals (∼ 55%). Fifteen different fuels with high octane numbers were tested six of which were primary reference fuels (PRF's) and nine were commercial fuels or reference fuels. The engine was operated at constant operational parameters (speed/load, valve timing and equivalence ratio, intake air temperature, compression ratio, etc.) changing only the fuel type while the engine was running. Changing the fuel affected the auto-ignition timing, represented by the 50% mass fraction burned location (CA50). However these changes were not consistent with the classical RON and MON numbers, which are measures of the knock resistance of the fuel. Indeed, no correlation was found between CA50 and the RON or MON numbers.

A validation study of the numerical model of n-heptane spray combustion based on experimental constant-volume data [1] was done, by comparing auto-ignition delays for different pre - turbulence levels and initial temperatures, flame contours, and soot distributions under Diesel-like conditions. The basic novelty of the methodology developed in [2] - [3] is the implementation of the partially stirred reactor (PaSR) model accounting for detailed chemistry / turbulence interactions. It is based on the assumption that the chemical processes proceed in two successive steps: micro mixing, simulated on a sub - grid scale, is followed by the reaction act. When the all Re number RNG k-ε or LES models are employed, the micro mixing time can be consistently defined giving the combustion model a “well-closed” form incorporated into the KIVA-3V code.

Substantial reduction of NOX and particulate emissions from diesel engines will be required by the emission legislation in the future. In a diesel engine, the combustion and emissions formation are governed by the spray formation and mixing processes. Parameters of importance are droplet size, droplet distribution, injection velocity, in-cylinder flow (convection and turbulence) and cylinder charge temperature/pressure. The mixing is controlled by convective and turbulent mixing due to in-cylinder charge motion, momentum transfer and turbulence induced by the injection process. The most important processes are known to be the turbulent macro- and micromixing. Smaller nozzle orifices are believed to increase mixing rate, due to smaller droplet size leading to faster evaporation. Dimensional analysis suggests that the turbulent mixing time, τmix, scales with orifice diameter, d.

A single cylinder, naturally aspirated, four-stroke and camless (Otto) engine was operated in homogeneous charge compression ignition (HCCI) mode with commercial gasoline. The valve timing could be adjusted during engine operation, which made it possible to optimize the HCCI engine operation for different speed and load points in the part-load regime of a 5-cylinder 2.4 liter engine. Several tests were made with differing combinations of speed and load conditions, while varying the valve timing and the inlet manifold air pressure. Starting with conventional SI combustion, the negative valve overlap was increased until HCCI combustion was obtained. Then the influences of the equivalence ratio and the exhaust valve opening were investigated. With the engine operating on HCCI combustion, unthrottled and without preheating, the exhaust valve opening, the exhaust valve closing and the intake valve closing were optimized next.

SI Engine knock is caused by autoignition in the unburnt part of the mixture (end-gas) ahead of the propagating flame. Autoignition of the end-gas occurs when the temperature and pressure exceeds a critical limit when comparatively slow reactions-releasing moderate amounts of heat-transform into ignition and rapid heat release. In this paper the difference in the heat released in the end-gas-by low temperature chemistry-between lean, rich, stochiometric, and stoichiometric mixtures diluted with cooled EGR was examined by measuring the temperature in the end-gas with Dual Broadband Rotational CARS. The measured temperature history was compared with an isentropic temperature calculated from the cylinder pressure trace. The experimentally obtained values for knock onset were compared with results from a two-zone thermodynamic model including detailed chemistry modeling of the end-gas reactions.

In a diesel engine, the combustion and emissions formation are governed by the spray formation and mixing processes. To meet the stringent emission legislations of the future, which will demand substantial reductions of NOX and particulate emissions from diesel engines, the spray and mixing processes play a major roll. Different fuel injection systems and injection strategies have been developed to achieve better performance and lower emissions from the diesel engine almost without investigating the influence of the injector nozzle orifices. A reduction in the nozzle orifice diameter is important for an increased mixing rate and formation of smaller droplets which is beneficial from emissions and fuel consumption point of view, as long as the local air-to-fuel ratio (AFR) is kept at a sufficiently lean level.

Projected stringent emissions legislation will make tough demands on engine development. For diesel engines, in which combustion and emissions formation are governed by the spray formation and mixing processes, fuel injection plays a major role in the future development of cleaner engines. It is therefore important to study the fundamental features of the fuel injection process. In an engine the fuel is injected at high pressure into a pressurized and hot environment of air, which causes droplet formation and fuel evaporation. The injected fuel then forms a gaseous phase surrounding the liquid phase. The amount of evaporated fuel in relation to the total amount of injected fuel is of importance for engine performance, i.e. ignition delay and mixing rate. In this paper, the fraction of evaporated fuel was determined for sprays, using different orifice diameters ranging from 0.100 mm up to 0.227 mm, with the aid of a high-pressure spray chamber.

This paper presents a follow on study from earlier work investigating the influence of fuel parameters on the deposit formation and emissions from a direct injection stratified charge spark ignition engine. It was shown that injector fouling was the main reason for the increase in unburned hydrocarbon emissions and spray visualizations supported these results. The hypothesis is that the deposit buildup in the injector caused the increased hydrocarbon emissions due to an increased wall film formation. To further verify the findings, Phase Doppler Anemometry measurements at simulated engine conditions, were performed. Measurements recorded on the injector axis 20 mm downstream from the injector orifice, showed that the initial pre-jet velocity was 30% higher and the drop mean diameter was 5% larger in the case of a used injector compared to a new injector. Based on these investigations, spray files were set-up in the 3-D CFD-code AVL FIRE™.

The effects of injection pressure and duration on exhaust gas emissions, sooting flame temperature, and soot distribution for a heavy–duty single cylinder DI diesel engine were investigated experimentally. The experimental analysis included use of two–color pyrometry as well as “conventional” measuring techniques. Optical access into the engine was obtained through an endoscope mounted in the cylinder head. The sooting flame temperature and soot distribution were evaluated from the flame images using the AVL VisioScope™ system. The results show that the NOx/soot trade–off curves could be improved by increasing injection pressure. An additional reduction could also be obtained if, for the same level of injection pressure, the injection duration was prolonged.

Passive selective catalyst reduction (SCR) systems can be used as aftertreatment systems for lean burn spark ignition (SI)-engines. Their operation is based on the interaction between the engine, an ammonia formation catalyst (AFC), and an SCR catalyst. Under rich conditions the AFC forms ammonia, which is stored in the SCR catalyst. Under lean conditions, the SCR catalyst reduces the engine out NOx using the stored NH3. This study compared the ammonia production and response times of a standard three way catalyst (TWC) and a Pd/Al2O3 catalyst under realistic engine operating conditions. In addition, the relationships between selected engine operating parameters and ammonia formation over a TWC were investigated, considering the influence of both the chosen load point and the engine settings.

Reducing emissions and improving efficiency are major goals of modern internal combustion engine research. The use of biomass-derived fuels in Diesel engines is an effective way of reducing well-to-wheels (WTW) greenhouse gas (GHG) emissions. Moreover, partially premixed combustion (PPC) makes it possible to achieve very efficient combustion with low emissions of soot and NOx. The objective of this study was to investigate the effect of using alcohol/Diesel blends or neat alcohols on emissions and thermal efficiency during PPC. Four alcohols were evaluated: n-butanol, isobutanol, n-octanol, and 2-ethylhexanol. The alcohols were blended with fossil Diesel fuel to produce mixtures with low cetane numbers (26-36) suitable for PPC. The blends were then tested in a single cylinder light duty (LD) engine. To optimize combustion, the exhaust gas recirculation (EGR) level, lambda, and injection strategy were tuned.

Diesel particulate filter (DPF) is the most effective emission control device for reducing particle emissions (both mass, PM, and number, PN) from diesel engines, however many studies reported elevated emissions of nanoparticles (<50 nm) during its regeneration. In this paper the results of an extensive literature survey is presented. During DPF active regeneration, most of the literature studies showed an increase in the number of the emitted nanoparticles of about 2-3 orders of magnitude compared to the normal operating conditions. Many factors could influence their amount, size distribution, chemical-physical nature (volatiles, semi-volatiles, solid) and the duration of the regenerative event: i.e. DPF load and thermodynamic conditions, lube and fuel sulfur content, engine operative conditions, PN sampling and measurement methodologies.

Laws concerning to emissions from heavy duty (HD) internal combustion engines are becoming increasingly stringent. New engine technologies are therefore needed to satisfy these new legal requirements and reduce fossil fuel dependency. One way to achieve both objectives is to partially replace fossil fuels with alternatives that are more sustainable with respect to emissions of greenhouse gas, particulates and NOx. As a first step towards the development of a direct injected dual fuel engine using diesel fuel and renewable alcohols such as methanol or ethanol, we have studied ethanol (E100) sprays generated with a standard high pressure diesel fuel injection system in a high pressure/temperature spray chamber with optical access. The experiments were performed at a gas density of ∼27kg/m3 at ∼550 °C and ∼60 bar, representing typical operating conditions for a HD engine at low loads.

In this paper, a parametric analysis on the main engine calibration parameters applied on gasoline Partially Premixed Combustion (PPC) is performed. Theoretically, the PPC concept permits to improve both the engine efficiencies and the NOx-soot trade-off simultaneously compared to the conventional diesel combustion. This work is based on the design of experiments (DoE), statistical approach, and investigates on the engine calibration parameters that might affect the efficiencies and the emissions of a gasoline PPC. The full factorial DoE analysis based on three levels and three factors (33 factorial design) is performed at three engine operating conditions of the Worldwide harmonized Light vehicles Test Cycles (WLTC). The pilot quantity (Qpil), the crank angle position when 50% of the total heat is released (CA50), and the exhaust gas recirculation (EGR) factors are considered. The goal is to identify an engine calibration with high efficiency and low emissions.